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Chemistry, chances and limitations of the radical ring-opening polymerization of cyclic ketene acetals for the synthesis of degradable polyesters

Titelangaben

Agarwal, Seema:
Chemistry, chances and limitations of the radical ring-opening polymerization of cyclic ketene acetals for the synthesis of degradable polyesters.
In: Polymer Chemistry. Bd. 1 (2010) Heft 7 . - S. 953-964.
ISSN 1759-9954
DOI: https://doi.org/10.1039/C0PY00040J

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Projektfinanzierung: Deutsche Forschungsgemeinschaft

Abstract

This article highlights the progress in the field of radical ring-opening polymerization (RROP) of cyclic ketene acetals for the synthesis of functionalised polyesters, (bio)degradable vinyl polymers, and speciality designed degradable polymers. The method of radical ring-opening polymerization offers the advantage in either making special functional polyesters which are not possible by conventional methods or for making polyesters for special applications where low volume shrinkage is of utmost importance. Furthermore, the beauty of radical ring-opening polymerization is in making a new class of degradable materials called poly(vinyl-co-ester)s. Having ester linkages distributed onto the vinyl polymer backbone is emphasised, no other method can combine vinyl polymer backbone with ester units in a random way. The method has opened new opportunities of using the known biomaterials for degradable applications. Other possibilities and challenges in using this method are making specialised degradable materials like ionomers and polymeric-inorganic hybrid materials, which are also discussed in detail.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: CONVENTIONAL VINYL MONOMERS; EPSILON-CAPROLACTONE; METHYL-METHACRYLATE; MICROSTRUCTURAL CHARACTERIZATION; HYDROLYTIC DEGRADATION; DELTA-VALEROLACTONE; TRIBLOCK COPOLYMERS; ETHYLENE CARBONATE; 5,6-BENZO-2-METHYLENE-1,3-DIOXEPANE; 2-METHYLENE-1,3-DIOXEPANE
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II > Lehrstuhl Makromolekulare Chemie II - Univ.-Prof. Dr. Andreas Greiner
Profilfelder > Advanced Fields > Polymer- und Kolloidforschung
Fakultäten
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Profilfelder
Profilfelder > Advanced Fields
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 02 Apr 2015 11:52
Letzte Änderung: 02 Apr 2015 11:52
URI: https://eref.uni-bayreuth.de/id/eprint/9883