at Google ScholarTitle data
Haas, Alois ; Willert-Porada, Monika:
Reactions of Trifluormethylthioamines with Reducing Agents.
In: Journal of Fluorine Chemistry.
Vol. 29
(1985)
Issue 1-2
.
- p. 158.
ISSN 1873-3328
DOI: https://doi.org/10.1016/S0022-1139(00)83394-1
Abstract in another language
Reactions of trifluoromethylthioamines (CF3S)3-nNHn with NaH (n = 0, 1, 2), NaBH4, NaNH2 (n = 1, 2) and NaOR (R = CH3, C2H5; n = 1) occur with differing sites of attack on the amin. Results of the NaH-reactions suggest that nucleophilic attack takes place at the hydrogen, nitrogen or sulphur atoms. With NaBH4 the amines CF3SNH2 and (CF3S)2NH behave as Lewis acids. In the presence of J2 as trapping- reagent for the hydride-ion the adduct (CF3S)2NH·BH3 could be isolated. Degradation of the amine occurs upon reaction with NaOR; however with NaNH2 an exchange reaction is observed. 15/14N-NMR-data for the trifluoromethylthioamines and several derivatives (silyl-, stannyl- and boric-) are presented.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Former Professors > Chair Electrochemical Process Engineering - Univ.-Prof. Dr. Monika Willert-Porada Faculties Faculties > Faculty of Engineering Science > Former Professors |
| Result of work at the UBT: | Yes |
| DDC Subjects: | 500 Science > 500 Natural sciences 600 Technology, medicine, applied sciences > 620 Engineering |
| Date Deposited: | 14 Aug 2017 07:35 |
| Last Modified: | 05 Jul 2022 11:50 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/11798 |