at Google ScholarTitle data
Willert-Porada, Monika ; Dennhöfer, S. ; Hachmeister, D.:
Microwave Pyrolysis of Emulsified Ceramic Precursor Compounds.
In: MRS Online Proceedings Library.
Vol. 347
(1994)
.
- pp. 571-577.
ISSN 1946-4274
DOI: https://doi.org/10.1557/PROC-347-571
Abstract in another language
Application of paraffin as a MW-transparent matrix for microwave pyrolysis of metalorganic compounds enables synthesis of large quantities of nanosized powders with excellent storability and packing behavior. Fully crystalline, nanosized t-ZrO₂ powders with specific surface area > 200 m²g⁻¹ are obtained from Zr-alcoholate, and alumina powders with > 500 m²g⁻¹ from Al-alcoholates. Some differences exist between microwave pyrolysis and conventional pyrolysis of such mixtures. Powders from microwave pyrolysis transform at lower calcination temperature to α-A1₂O₃ and exhibit after calcination a more homogeneous morphology as compared to powders from conventional pyrolysis. Furthermore, a different composition of the volatile pyrolysis products is found. t-ZrO₂ powder from the microwave processing route exhibits an increased stability towards transformation to monoclinic ZrO₂ as well as smaller initial grain sizes than a conventionally synthesized powder.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Former Professors > Chair Electrochemical Process Engineering - Univ.-Prof. Dr. Monika Willert-Porada Faculties Faculties > Faculty of Engineering Science > Former Professors |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 500 Natural sciences 600 Technology, medicine, applied sciences > 620 Engineering |
| Date Deposited: | 24 Aug 2017 06:54 |
| Last Modified: | 22 Dec 2023 09:37 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/11813 |