Title data
Scheuermeyer, Marlene ; Kusche, Matthias ; Agel, Friederike ; Schreiber, Patrick ; Maier, Florian Johannes ; Steinrück, Hans-Peter ; Davis, James H. ; Heym, Florian ; Jess, Andreas ; Wasserscheid, Peter:
Thermally stable bis(trifluoromethylsulfonyl)imide salts and their mixtures.
In: New Journal of Chemistry.
Vol. 40
(2016)
Issue 8
.
- pp. 7157-7161.
ISSN 1369-9261
DOI: https://doi.org/10.1039/C6NJ00579A
Abstract in another language
We show that both tetraphenylphosphonium bis(trifluoromethylsulfonyl)imide ([PPh4][NTf2]) and Cs[NTf2] are low melting salts of exceptionally high and also very similar thermal stability. This similarity indicates that the thermal stability is dominated by the anion. Moreover, eutectic mixtures of [PPh4][NTf2] and Cs[NTf2] with melting points below 100 [degree]C are presented. Surface analysis of the latter in the liquid state reveals a surprising depletion of [PPh4]+ ions from the surface.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Chemical Engineering Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess Faculties |
Result of work at the UBT: | Yes |
DDC Subjects: | 500 Science > 540 Chemistry 600 Technology, medicine, applied sciences > 600 Technology 600 Technology, medicine, applied sciences > 620 Engineering 600 Technology, medicine, applied sciences > 660 Chemical engineering |
Date Deposited: | 11 Aug 2016 06:39 |
Last Modified: | 09 Jan 2025 14:36 |
URI: | https://eref.uni-bayreuth.de/id/eprint/34087 |