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Actuating Porous Polyimide Films

Titelangaben

Zhang, Yaoming ; Ionov, Leonid:
Actuating Porous Polyimide Films.
In: ACS Applied Materials & Interfaces. Bd. 6 (2014) Heft 13 . - S. 10072-10077.
ISSN 1944-8252
DOI: https://doi.org/10.1021/am502492u

Abstract

We report a novel method for the fabrication of one-component self-folding polymer films. The approach is based on films with a vertical gradient of porosity and was demonstrated on an example of porous polyimide films. The inhomogeneous porosity of the films was achieved through the implementation of capillary forces and gravity during the drying of a dispersion of colloidal particles in a solution of polymer precursor. As a result, three-layered films were formed. A monolayer of particles comprises the top layer, the second layer is the pure polymer, and the third layer is formed by a mixture of particles and polymer. Etching out the particles leaves polyimide film with inhomogeneous distributed pores. These porous polymer films roll and form tubes in organic solvents as well as their vapors and reversibly unfold in air. The obtained films were used for design of actuators, which are able to capture and release different objects through the reversible folding.We report a novel method for the fabrication of one-component self-folding polymer films. The approach is based on films with a vertical gradient of porosity and was demonstrated on an example of porous polyimide films. The inhomogeneous porosity of the films was achieved through the implementation of capillary forces and gravity during the drying of a dispersion of colloidal particles in a solution of polymer precursor. As a result, three-layered films were formed. A monolayer of particles comprises the top layer, the second layer is the pure polymer, and the third layer is formed by a mixture of particles and polymer. Etching out the particles leaves polyimide film with inhomogeneous distributed pores. These porous polymer films roll and form tubes in organic solvents as well as their vapors and reversibly unfold in air. The obtained films were used for design of actuators, which are able to capture and release different objects through the reversible folding.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation > Professur Biofabrikation - Univ.-Prof. Dr. Leonid Ionov
Fakultäten
Fakultäten > Fakultät für Ingenieurwissenschaften
Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 20 Jun 2017 12:29
Letzte Änderung: 10 Mär 2022 10:06
URI: https://eref.uni-bayreuth.de/id/eprint/37699