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Herling, Markus M. ; Lacher, Ulrike ; Rieß, Martin ; Seibt, Sebastian ; Schwedes, Mathias ; Kalo, Hussein ; Schobert, Rainer ; Breu, Josef:
Sub-micron pore size tailoring for efficient chiral discrimination.
In: Chemical Communications.
Bd. 53
(2017)
Heft 6
.
- S. 1072-1075.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C6CC09484H
Abstract
Adsorption studies in microporous organically pillared layered silicates (MOPS) show that precise control of micropore size in the sub-Ångström range is crucial for chiral discrimination. The highly modular character of MOPS generally allows for an optimization of guest recognition without the need to explore different framework topologies.