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Polarization Dependence of the C 1s X-ray Absorption Spectra of Individual Multi-Walled Carbon Nanotubes

Title data

Najafi, Ebrahim ; Cruz, Daniel Hernández ; Obst, Martin ; Hitchcock, Adam P. ; Douhard, Bastien ; Pireux, Jean-Jacques ; Felten, Alexandre:
Polarization Dependence of the C 1s X-ray Absorption Spectra of Individual Multi-Walled Carbon Nanotubes.
In: Small. Vol. 4 (2008) Issue 12 . - pp. 2279-2285.
ISSN 1613-6829
DOI: https://doi.org/10.1002/smll.200800439

Abstract in another language

The polarization dependence (linear dichroism) of the C 1s X-ray absorption spectrum of individual multi-walled carbon nanotubes (MWCNTs) is measured using scanning transmission X-ray microscopy. A very strong dichroic effect is found in the C 1s → π* transition, with almost complete disappearance of this transition when the electric-field (E)-vector is aligned parallel to high-quality (low-defect) MWCNTs and maximum intensity when the E-vector is orthogonal to the tube axis. In contrast, there is very little dichroism in the C 1s → σ* transitions. The origin of this polarization effect is explained. The magnitude of the polarization dependence is found to differ in MWCNTs synthesized by different methods (arc discharge versus chemical vapor deposition). This is ascribed to differences in densities of sp2-type defects. The potential for use of this signal to characterize defects in single-carbon-nanotube devices is discussed.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: BAYCEER135599
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Earth Sciences > Heisenberg Professorship - Experimental Biogeochemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Earth Sciences > Heisenberg Professorship - Experimental Biogeochemistry > Heisenberg Professorship - Experimental Biogeochemistry - Univ.-Prof. Dr. Martin Obst
Research Institutions
Research Institutions > Research Centres
Research Institutions > Research Centres > Bayreuth Center of Ecology and Environmental Research- BayCEER
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Earth Sciences
Result of work at the UBT: No
DDC Subjects: 500 Science
Date Deposited: 13 Aug 2020 13:20
Last Modified: 27 Aug 2021 09:46
URI: https://eref.uni-bayreuth.de/id/eprint/56496