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Strohriegl, Peter ; Wagner, Daniel ; Schrögel, Pamela ; Hoffmann, Sebastian T. ; Köhler, Anna ; Heinemeyer, Ute ; Münster, Ingo:
Novel host materials for blue phosphorescent OLEDs.
In:
So, Franky (Hrsg.): Organic light emitting materials and devices XVII. -
Bellingham, Washington
: SPIE
,
2013
. - No. 882906
. - (Proceedings of SPIE
; 8829
)
ISBN 9780819496799
DOI: https://doi.org/10.1117/12.2023305
Abstract
We present two classes of host materials for blue phosphors. The first are carbazole substituted biphenyls 1-9. In these CBP-type materials the triplets are confined to one half of the molecules by using either twisted biphenyls or by a metalinkage of the carbazoles to the biphenyl. We obtained high triplet energies of 2.95-2.98 eV and high glass transition temperatures in the range of 100-120 °C. OLEDs were fabricated using the host material 6 and the carbene emitter Ir(dbfmi) with pure blue emission at 450 nm. The devices achieved an external quantum efficiency of 8.7% at 100 cd/m2 and 6.1% at 1000 cd/m2. MBPTRZ with an electron transporting biscarbazolyltriazine that is separated from the hole transporting carbazole by a non-conjugated, meta-linked biphenyl unit is an example for a bipolar matrix material. The excellent glass forming properties and the high Tg of 132 °C ensure morphological stability in OLEDs. The meta-linkage and the additional twist at the biphenyl unit, which is achieved by two methyl groups in the 2- and 2’-position of the biphenyl in MBPTRZ leads to a decoupling of the electron accepting and electron donating part and therefore to a high triplet energy of 2.81 eV. DFT calculations show a clear separation of the electron and hole transporting moieties. A phosphorescent OLED with MBPTRZ as host and FIrpic as emitter reached a maximum external quantum efficiency of 7.0%, a current efficiency of 16.3 cd/A and a power efficiency of 6.3 lm/W. © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Weitere Angaben
| Publikationsform: | Aufsatz in einem Buch |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie - Univ.-Prof. Dr. Anna Köhler Fakultäten Fakultäten > Fakultät für Mathematik, Physik und Informatik Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie |
| Titel an der UBT entstanden: | Ja |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 530 Physik |
| Eingestellt am: | 18 Mär 2015 07:37 |
| Letzte Änderung: | 29 Mai 2024 11:23 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/6244 |