Title data
Rietsch, Philipp ; Zeyat, Mohammad ; Hübner, Oskar ; Hoffmann, Katrin ; Kutter, Maximilian ; Paskin, Alice ; Uhlig, Julian ; Lentz, Dieter ; Resch-Genger, Ute ; Eigler, Siegfried:
Substitution Pattern-Controlled Fluorescence Lifetimes of Fluoranthene Dyes.
In: The Journal of Physical Chemistry B.
Vol. 125
(2021)
Issue 4
.
- pp. 1207-1213.
ISSN 1520-5207
DOI: https://doi.org/10.1021/acs.jpcb.0c08851
Abstract in another language
The absorption and emission properties of organic dyes are generally tuned by altering the substitution pattern. However, tuning the fluorescence lifetimes over a range of several 10 ns while barely affecting the spectral features and maintaining a moderate fluorescence quantum yield is challenging. Such properties are required for lifetime multiplexing and barcoding applications. Here, we show how this can be achieved for the class of fluoranthene dyes, which have substitution-dependent lifetimes between 6 and 33 ns for single wavelength excitation and emission. We explore the substitution-dependent emissive properties in the crystalline solid state that would prevent applications. Furthermore, by analyzing dye mixtures and embedding the dyes in carboxy-functionalized 8 μm-sized polystyrene particles, the unprecedented potential of these dyes as labels and encoding fluorophores for time-resolved fluorescence detection techniques is demonstrated.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering > Chair Electrochemical Process Engineering - Univ.-Prof. Dr. Christina Roth Faculties Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering |
Result of work at the UBT: | No |
DDC Subjects: | 500 Science > 540 Chemistry 600 Technology, medicine, applied sciences > 620 Engineering |
Date Deposited: | 20 Apr 2021 10:49 |
Last Modified: | 20 Apr 2021 10:49 |
URI: | https://eref.uni-bayreuth.de/id/eprint/64813 |