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Characterization of different Pt/Metal/Complex catalysts as anode catalysts for the PEM fuel cell

Title data

Martz, N. ; Roth, Christina ; Fuess, H.:
Characterization of different Pt/Metal/Complex catalysts as anode catalysts for the PEM fuel cell.
In: Journal of Applied Electrochemistry. Vol. 35 (2005) Issue 1 . - pp. 85-90.
ISSN 1572-8838
DOI: https://doi.org/10.1007/s10800-004-4059-9

Abstract in another language

Different Pt/Me/Pc and Pt/Me/Complex catalysts (with Me=Metal: Co, Ni, and Pc=phthalocyanine) were synthesized by an impregnation method. A commercially available platinum catalyst purchased from E-TEK. was impregnated with solutions of cobalt phthalocyanine (CoPc) and nickel phthalocyanine tetrasulfonic salt (NiPc). After the reaction, part of the catalyst was heat treated at 700 °C under nitrogen atmosphere. The resulting catalysts were structurally and electrochemically characterized before (Pt/Me/Pc) and after heat treatment (Pt/Me/Complex). The Pt/Me/Pc had an average particle size of about 3 nm, while the average size after heat treatment increased to about 7nm. The composition of the different catalysts was about 80at platinum and 20at of the second metal (Co or Ni), and was verified with EDXS. In single fuel cell tests the best electrocatalytic activity was observed for the Pt/Ni/Complex system.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering > Chair Electrochemical Process Engineering - Univ.-Prof. Dr. Christina Roth
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 22 Apr 2021 11:29
Last Modified: 29 Jun 2022 09:07
URI: https://eref.uni-bayreuth.de/id/eprint/64881