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Porous N- and S-doped carbon–carbon composite electrodes by soft-templating for redox flow batteries

Title data

Schnucklake, Maike ; Eifert, László ; Schneider, Jonathan ; Zeis, Roswitha ; Roth, Christina:
Porous N- and S-doped carbon–carbon composite electrodes by soft-templating for redox flow batteries.
In: Beilstein Journal of Nanotechnology. Vol. 10 (2019) . - pp. 1131-1139.
ISSN 2190-4286
DOI: https://doi.org/10.3762/bjnano.10.113

Abstract in another language

Highly porous carbon–carbon composite electrodes for the implementation in redox flow battery systems have been synthesized by a novel soft-templating approach. A PAN-based carbon felt was embedded into a solution containing a phenolic resin, a nitrogen source (pyrrole-2-carboxaldehyde) and a sulfur source (2-thiophenecarboxaldehyde), as well as a triblock copolymer (Pluronic® F-127) acting as the structure-directing agent. By this strategy, highly porous carbon phase co-doped with nitrogen and sulfur was obtained inside the macroporous carbon felt. For the investigation of electrode structure and porosity X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and nitrogen sorption (BET) were used. The electrochemical performance of the carbon felts was evaluated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The N- and S-doped carbon electrodes show promising activity for the positive side reaction and could be seen as a significant advance in the design of carbon felt electrodes for use in redox flow batteries.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: N- and S-doped carbon; porous electrode; redox flow battery; soft-templating approach; vanadium
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering > Chair Electrochemical Process Engineering - Univ.-Prof. Dr. Christina Roth
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Electrochemical Process Engineering
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 28 Apr 2021 11:03
Last Modified: 28 Apr 2021 11:03
URI: https://eref.uni-bayreuth.de/id/eprint/64970