at Google ScholarTitle data
Bringmann, Gerhard ; Pfeifer, Robert-Michael ; Schreiber, Petra ; Hartner, Kristina ; Schraut, Michaela ; Breuning, Matthias:
The "lactone method" : enantioselective preparation of novel P,N-biaryl ligands and their use in the synthesis of the biarylic alkaloids, ancistrotanzanine B and ancistroealaine A.
In: Tetrahedron.
Vol. 60
(2004)
Issue 20
.
- pp. 4349-4360.
ISSN 0040-4020
DOI: https://doi.org/10.1016/j.tet.2003.12.070
Abstract in another language
The ‘lactone method’ is a versatile tool for the atroposelective synthesis of axially chiral biaryls. The potential and scope of the concept are highlighted, in particular with respect to its use in the preparation of natural products and chiral auxiliaries. As a new application, the synthesis of novel axially chiral phosphineamines in enantiopure form is described; these ligands were used in the asymmetric Suzuki cross coupling of the molecular portions of the biarylic natural products ancistrotanzanine B and ancistroealaine A.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Axially chiral biaryls; P,N-Ligands; Asymmetric Suzuki coupling; Natural product synthesis; Naphthylisoquinoline alkaloids |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry > Professor Organic Chemistry - Univ.-Prof. Dr. Matthias Breuning Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Organic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 12 Jan 2022 07:56 |
| Last Modified: | 12 Jan 2022 07:56 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/68327 |