at Google ScholarTitle data
Chen, Qianlin ; Yan, Wen ; Yan, Junjie ; Schafföner, Stefan ; Chen, Zhe ; Ma, Sanbao ; Li, Guangqiang:
Microstructures and strengths of microporous MgO–Al₂O₃ ceramics from Al(OH)₃ and calcined magnesite.
In: Journal of the American Ceramic Society.
Vol. 105
(2022)
Issue 12
.
- pp. 7741-7750.
ISSN 1551-2916
DOI: https://doi.org/10.1111/jace.18683
Abstract in another language
Seven microporous MgO–Al2O3 ceramics with an Al2O3 content of 15–90 wt% were prepared using Al(OH)3 and calcined magnesite as raw materials. A wet mixing process was employed during sample preparation to transform the calcined magnesite with a larger particle size to smaller Mg(OH)2 particles. The in situ decomposition synthesis method and the Kirkendall effect were utilized to produce and control the pore structure of the microporous MgO–Al2O3 ceramics. There were two kinds of pores in the microporous MgO–Al2O3 ceramics. The first one resulted from the in situ decomposition of Al(OH)3 and Mg(OH)2 particles, which were small and equally distributed. Another one originated from the position of the Mg(OH)2 particles due to the Kirkendall effect caused by MgO diffusion. They were similar in size to the Mg(OH)2 pseudomorph particles. Simultaneously, the Al2O3 content affected the packing behavior and the spinel formation, which changed the characteristics of the pores and necks among the particles. These mechanisms also affected the strengths of the microporous MgO–Al2O3 ceramics. Thus, when the Al2O3 content was 45–90 wt%, the microporous MgO–Al2O3 ceramics had a high compressive strength (10.0–18.3 MPa) and apparent porosity (52.2%–58.4%).
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | in situ decomposition synthesis method; Kirkendall effect; microporous MgO–Al2O3 ceramics; microstructures |
| Institutions of the University: | Faculties Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Ceramic Materials > Chair Ceramic Materials - Univ.-Prof. Dr.-Ing. Stefan Schafföner Faculties > Faculty of Engineering Science > Chair Ceramic Materials |
| Result of work at the UBT: | No |
| DDC Subjects: | 600 Technology, medicine, applied sciences 600 Technology, medicine, applied sciences > 620 Engineering |
| Date Deposited: | 31 Mar 2023 09:01 |
| Last Modified: | 31 Mar 2023 09:01 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/75723 |