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Investigation of calcium zirconate formation by sintering zirconium dioxide with calcium hydroxide

Title data

Jahn, Constantin ; Schafföner, Stefan ; Ode, Christian ; Jansen, Helge ; Aneziris, Christos G.:
Investigation of calcium zirconate formation by sintering zirconium dioxide with calcium hydroxide.
In: Ceramics International. Vol. 44 (2018) Issue 10 . - pp. 11274-11281.
ISSN 1873-3956
DOI: https://doi.org/10.1016/j.ceramint.2018.03.172

Abstract in another language

The present paper analysed the formation of calcium zirconate from zirconium dioxide and calcium hydroxide through solid state reaction. Different mole ratios and sintering temperatures are investigated. The sintering temperature was reduced to 1200 °C. Due to the decomposition process of the calcia source during firing the volume expansion in the sintered samples was remarkable. A good homogenisation of the raw mixture is necessary to obtain a complete reaction of the material. The microstructure of the calcium zirconate gained from calcium hydroxide and from calcium carbonate did not differ. Moreover, a difference in reactivity due to varying microstructure and temperature of decomposition between the different calcia sources could not be determined. Thus calcium carbonate is less hazardous and resulted in a higher yield of calcium zirconate compared to calcium hydroxide as calcia source.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Ceramic Materials
Faculties > Faculty of Engineering Science > Chair Ceramic Materials > Chair Ceramic Materials - Univ.-Prof. Dr.-Ing. Stefan Schafföner
Result of work at the UBT: No
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 25 May 2023 09:54
Last Modified: 25 May 2023 09:54
URI: https://eref.uni-bayreuth.de/id/eprint/76188