at Google ScholarTitle data
Schafföner, Stefan ; Fruhstorfer, Jens ; Faßauer, Christina ; Freitag, Lisa ; Jahn, Constantin ; Aneziris, Christos G.:
Influence of in situ phase formation on properties of calcium zirconate refractories.
In: Journal of the European Ceramic Society.
Vol. 37
(2017)
Issue 1
.
- pp. 305-313.
ISSN 0955-2219
DOI: https://doi.org/10.1016/j.jeurceramsoc.2016.08.017
Abstract in another language
This study investigates chemical, physical, mechanical, and thermomechanical properties of calcium zirconate (CaZrO3) refractories. The applied fused raw material contained some residual cubic zirconia, which impairs the corrosion resistance of CaZrO3 refractories. To adjust the stoichiometry, CaCO3 was added. Furthermore, stoichiometric amounts of CaCO3/monoclinic ZrO2 were added to promote an in situ pore formation without altering the phase composition. After firing cubic zirconia was only found in the coarse grained aggregates. CaCO3 additions increased the apparent porosity and reduced the thermal expansion coefficient due to the stoichiometric adjustment. Surprisingly, a higher porosity did not result in an improved thermal shock resistance, which can be attributed to a shift to larger pore sizes. This might cause a lower crack density, which is usually associated with a reduced thermal shock resistance. Future work will address the formation of smaller pores and the evaluation of the thermal shock resistance under practical conditions.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | Calcium zirconate; Refractories; Thermal shock resistance; Elastic properties; Thermal expansion coefficient |
| Institutions of the University: | Faculties Faculties > Faculty of Engineering Science Faculties > Faculty of Engineering Science > Chair Ceramic Materials Faculties > Faculty of Engineering Science > Chair Ceramic Materials > Chair Ceramic Materials - Univ.-Prof. Dr.-Ing. Stefan Schafföner |
| Result of work at the UBT: | No |
| DDC Subjects: | 600 Technology, medicine, applied sciences 600 Technology, medicine, applied sciences > 620 Engineering |
| Date Deposited: | 25 May 2023 07:46 |
| Last Modified: | 25 May 2023 07:46 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/76255 |