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Fused calcium zirconate for refractory applications

Title data

Schafföner, Stefan ; Aneziris, Christos G. ; Berek, Harry ; Hubálková, Jana ; Priese, Angelika:
Fused calcium zirconate for refractory applications.
In: Journal of the European Ceramic Society. Vol. 33 (2013) Issue 15-16 . - pp. 3411-3418.
ISSN 0955-2219
DOI: https://doi.org/10.1016/j.jeurceramsoc.2013.07.008

Abstract in another language

This article investigates dense CaZrO3 produced by electric arc melting and compares it to solid state synthesized CaZrO3. The fused CaZrO3 had a considerable lower porosity than the solid state synthesized material, however due to evaporation of some CaO during the electric arc melting the stoichiometric ratio of CaO/ZrO2 was slightly smaller than one, resulting in the formation of cubic ZrO2 as a second phase. To determine the local phase distribution the materials were investigated with EBSD in addition to integral XRD. The vibration polishing of the ceramics resulted in excellent EBSD patterns. Die pressed cylinders of the fused material led to a porosity as low as 14.3%. The linear thermal expansion coefficient from 25 °C to 1000 °C was 10.45 × 10−6 K−1. The cold isostatic pressing of larger crucibles resulted in higher porosity of 15.9–16.5%. The EBSD analysis and the cold isostatic pressed crucibles can be applied in corrosion tests for titanium melts.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Calcium zirconate; EBSD; Refractories; X-ray computed tomography; Cold isostatic pressing
Institutions of the University: Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Ceramic Materials
Faculties > Faculty of Engineering Science > Chair Ceramic Materials > Chair Ceramic Materials - Univ.-Prof. Dr.-Ing. Stefan Schafföner
Result of work at the UBT: No
DDC Subjects: 600 Technology, medicine, applied sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 25 May 2023 07:39
Last Modified: 25 May 2023 07:39
URI: https://eref.uni-bayreuth.de/id/eprint/76264