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Self-Assembly of block copolymers into internally ordered microparticles

Title data

Wong, Chin Ken ; Qiang, Xiaolian ; Müller, Axel H. E. ; Gröschel, André H.:
Self-Assembly of block copolymers into internally ordered microparticles.
In: Progress in Polymer Science. Vol. 102 (2020) . - 101211.
ISSN 0079-6700
DOI: https://doi.org/10.1016/j.progpolymsci.2020.101211

Abstract in another language

Block copolymer (BCP) self-assembly is one of the most versatile concepts for the bottom-up design of functional nanostructures in materials science, nanomedicine and nanotechnology. While BCPs have been extensively studied regarding their microphase separation in bulk and the self-assembly in solution, only recently BCPs were investigated for their ability to form internally ordered microparticles. In this review, we discuss two emerging concepts: (i) the microphase separation of BCPs in the spherical confinement of evaporating emulsion droplets and (ii) the self-assembly of highly asymmetric BCPs under concentrated conditions. While the first concept yields solid and compact multicompartment microparticles suited for the synthesis of shape-anisotropic nanoparticles, photonic colloids, and actuators, the latter produces highly regular porous microparticles with exceptional interfacial area (BCP cubosomes and hexosomes). Despite distinct differences in the origin of both fields, commonalities in shape and morphology suggest an underlying formation mechanism that may link both research directions.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Research Institutions > Central research institutes > Bayerisches Zentrum für Batterietechnik - BayBatt
Research Institutions
Research Institutions > Central research institutes
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Polymer Materials for Electrochemical Storage > Chair Polymer Materials for Electrochemical Storage - Univ.-Prof. Dr. André Gröschel
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 24 Jul 2023 13:17
Last Modified: 02 Aug 2023 07:53
URI: https://eref.uni-bayreuth.de/id/eprint/86308