at Google ScholarTitle data
Chen, Chen ; Wong, Chin Ken ; Gröschel, André H.:
Mixtures of Acid‐ and Base‐Functionalized Microparticles for One‐Pot Cascade Reaction.
In: Macromolecular Rapid Communications.
Vol. 44
(2023)
Issue 12
.
- 2300063.
ISSN 1521-3927
DOI: https://doi.org/10.1002/marc.202300063
Abstract in another language
This study reports on the synthesis of surface-protected acid and base microparticles via surfactant-free emulsion polymerization. The protective layer allows to form particle mixtures with both colloidal catalysts that show excellent performance in a well-established model cascade reaction involving an acid-catalyzed deacetalization and a subsequent base-catalyzed Knoevenagel condensation. Compared to nanoreactors that contain both catalysts, the colloidal mixture shows comparable reaction kinetics despite the local separation of both catalysts onto separate particles. Since the synthesis of individual microparticles requires less steps, is scalable, and more versatile in terms of catalyst variation, colloidal mixtures are certainly an alternative to multifunctional nanoreactors, making them attractive for practical applications.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Research Institutions > Central research institutes > Bayerisches Zentrum für Batterietechnik - BayBatt Research Institutions Research Institutions > Central research institutes Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Polymer Materials for Electrochemical Storage > Chair Polymer Materials for Electrochemical Storage - Univ.-Prof. Dr. André Gröschel |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 27 Jul 2023 11:02 |
| Last Modified: | 02 Aug 2023 07:53 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/86370 |