at Google ScholarTitle data
Ghosh, Swarup ; Glöckler, Eduard ; Wölper, Christoph ; Linders, Jürgen ; Janoszka, Nicole ; Gröschel, André H. ; Schulz, Stephan:
Comparison of the Catalytic Activity of Mono‐ and Multinuclear Ga Complexes in the ROCOP of Epoxides and Cyclic Anhydrides.
In: European Journal of Inorganic Chemistry.
Vol. 2022
(2022)
Issue 3
.
- e202101017.
ISSN 1099-0682
DOI: https://doi.org/10.1002/ejic.202101017
Abstract in another language
Tetranuclear Schiff-base complexes L1–32Ga4(t-Bu)8 1–3 are highly active and selective (>99 %) catalyst in the alternating ring-opening copolymerization (ROCOP) of epoxides and anhydrides, yielding polyesters with high molecular weights (Mn) and narrow dispersity (Đ). The thermal properties (Tg) of the resulting polyester range from 18 °C to 124 °C and increase with increasing steric bulk or rigidity along the polymer backbone. Comparative studies using structurally related complexes L4Ga(t-Bu)2 4, [L5GaR2]2 (R=t-Bu 5, R=Me 6) and L6Ga(t-Bu)2 7 proved that the Ga2O2 core of catalyst 1 is the catalytically active species.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Institutions of the University: | Research Institutions > Central research institutes > Bayerisches Zentrum für Batterietechnik - BayBatt Research Institutions Research Institutions > Central research institutes Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Polymer Materials for Electrochemical Storage > Chair Polymer Materials for Electrochemical Storage - Univ.-Prof. Dr. André Gröschel |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 27 Jul 2023 12:39 |
| Last Modified: | 02 Aug 2023 07:53 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/86380 |