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Emission modulation of fluorescent turn-on mode dibenzothienyl sulfonyl ethene photoswitches embedded in a polymer film

Title data

Albert, Andrea ; Fried, Martina ; Thelakkat, Mukundan ; Köhler, Jürgen:
Emission modulation of fluorescent turn-on mode dibenzothienyl sulfonyl ethene photoswitches embedded in a polymer film.
In: Physical Chemistry Chemical Physics. Vol. 24 (2022) Issue 48 . - pp. 29791-29800.
ISSN 1463-9084
DOI: https://doi.org/10.1039/d2cp05062e

Abstract in another language

For decades photochromic molecules have attracted attention for their potential in using light as an external stimulus to change their photophysical properties. Here we report the spectroscopic characterization of two emissive photochromic molecules that are intrinsically fluorescent and that undergo a photocyclization/cycloreversion reaction upon illumination with light in the UV and VIS spectral ranges. For appropriately adjusted illumination intensities the emission can be modulated between the high- and the low-level with a contrast ratio exceeding 80%. The data are in reasonable agreement with the predictions from a simple kinetic model.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics IX - Spectroscopy of Soft Matter > Chair Experimental Physics IX - Spectroscopy of Soft Matter - Univ.-Prof. Dr. Jürgen Köhler
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I
Research Institutions > Central research institutes > Bayreuth Institute of Macromolecular Research - BIMF
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 02 Aug 2023 05:30
Last Modified: 02 Aug 2023 06:24
URI: https://eref.uni-bayreuth.de/id/eprint/86460