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Purely Optical, Reversible, Read-Write-Erase Cycling Using Photoswitchable Beads in Micropatterned Arrays

Title data

Zhang, Heyou ; Dharpure, Pankaj ; Philipp, Michael ; Mulvaney, Paul ; Thelakkat, Mukundan ; Köhler, Jürgen:
Purely Optical, Reversible, Read-Write-Erase Cycling Using Photoswitchable Beads in Micropatterned Arrays.
In: Advanced Optical Materials. Vol. 12 (2024) Issue 26 . - 2401029.
ISSN 2195-1071
DOI: https://doi.org/10.1002/adom.202401029

Official URL: Volltext

Project information

Project title:
Project's official title
Project's id
solar technologies go hybrid
No information

Project financing: Bayerisches Staatsministerium für Wissenschaft, Forschung und Kunst
Deutsche Forschungsgemeinschaft

Abstract in another language

Using surface-templated electrophoretic deposition, arrays of polymer beads (photonic units) incorporating photo-switchable DAE molecules are created, which can be reversibly and individually switched between high and low emission states by direct photo-excitation, without any energy or electron transfer processes within the molecular system. The micropatterned array of these photonic units is spectroscopically characterized in detail and optimized with respect to both signal contrast and cross-talk. The optimum optical parameters including laser intensity, wavelength and duration of irradiation are elucidated and ideal conditions for creating reversible on/off cycles in a micropatterned array are determined. 500 such cycles are demonstrated with no obvious on/off contrast attenuation. The ability to process binary information is demonstrated by selectively writing information to the given photonic unit, reading the resultant emissive signal pattern and finally erasing the information again, which in turn demonstrates the possibility of continuous recording. This basic study paves the way for building complex circuits using spatially well-arranged photonic units.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: micro patterned arrays; photo switchable polymer beads; photochromism; photonic logic gates
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics IX - Spectroscopy of Soft Matter > Chair Experimental Physics IX - Spectroscopy of Soft Matter - Univ.-Prof. Dr. Jürgen Köhler
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Applied Functional Polymers > Professor Applied Functional Polymers - Univ.-Prof. Dr. Mukundan Thelakkat
Research Institutions > Central research institutes > Bayreuth Institute of Macromolecular Research - BIMF
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics
Faculties > Faculty of Mathematics, Physics und Computer Science > Department of Physics > Chair Experimental Physics IX - Spectroscopy of Soft Matter
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Professor Applied Functional Polymers
Research Institutions
Research Institutions > Central research institutes
Research Institutions > Affiliated Institutes
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 12 Oct 2024 21:00
Last Modified: 26 Nov 2024 07:05
URI: https://eref.uni-bayreuth.de/id/eprint/90679