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The ΔQ-method : State of health and degradation mode estimation for lithium-ion batteries using a mechanistic model with relaxed voltage points

Title data

Hofmann, Tobias ; Li, Jiahao ; Hamar, Jacob ; Erhard, Simon ; Schmidt, Jan Philipp:
The ΔQ-method : State of health and degradation mode estimation for lithium-ion batteries using a mechanistic model with relaxed voltage points.
In: Journal of Power Sources. Vol. 596 (2024) . - 234107.
ISSN 0378-7753
DOI: https://doi.org/10.1016/j.jpowsour.2024.234107

Official URL: Volltext

Abstract in another language

Lithium-ion batteries exhibit path-dependent aging behavior. Degradation mode (DM) estimation is a first step towards accurate state of health (SOH) representations by clustering degradation mechanisms. Mechanistic models shift and scale pristine half-cell open circuit potential (OCP) curves of both electrodes to reconstruct the open circuit voltage (OCV) curve by minimizing the difference between measured and reconstructed OCV. Alignment parameters describe the shift and scaling of the OCPs and can be used to estimate SOH and DMs. This study introduces the ΔQ-method, which relies on relaxed voltage points and accumulated charge between these points. It is independent of current rates and applicable after almost every event. The optimization problem minimizes deviation between measured and reconstructed ΔQ. The method is developed with an automotive cell dataset and validated with real-world vehicle data from the BMW i3. The ΔQ-method achieves a mean absolute SOH estimation error of 2.52 and a mean absolute OCV reconstruction error of 7.19mV. Reliable estimations are ensured by predefined filters. The method remains effective with restricted state of charge (SOC) windows or limited data points. It is robust against variations in input data, solver choice, and optimization settings. Convergence is improved by constraining the solution space.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Lithium-ion battery; State of health estimation; Degradation modes; OCV curve; Mechanistic model; Relaxed voltage points; Battery electric vehicle; Partial charging
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Systems Engineering for Electrical Energy Storage > Chair Systems Engineering for Electrical Energy Storage - Univ.-Prof. Dr. Jan Philipp Schmidt
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Systems Engineering for Electrical Energy Storage
Result of work at the UBT: Yes
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 19 Oct 2024 21:00
Last Modified: 21 Oct 2024 08:38
URI: https://eref.uni-bayreuth.de/id/eprint/90762