at Google ScholarTitle data
Aslandukov, Andrii ; Liang, Akun ; Ehn, Amanda ; Trybel, Florian ; Yin, Yuqing ; Aslandukova, Alena ; Akbar, Fariia Iasmin ; Ranieri, Umbertoluca ; Spender, James ; Howie, Ross T. ; Bright, Eleanor Lawrence ; Wright, Jonathan ; Hanfland, Michael ; Garbarino, Gaston ; Mezouar, Mohamed ; Fedotenko, Timofey ; Abrikosov, Igor A. ; Dubrovinskaia, Natalia ; Dubrovinsky, Leonid ; Laniel, Dominique:
Synthesis of LaCN₃, TbCN₃, CeCN5, and TbCN₅ Polycarbonitrides at Megabar Pressures.
In: Journal of the American Chemical Society.
Vol. 146
(2024)
Issue 26
.
- pp. 18161-18171.
ISSN 1520-5126
DOI: https://doi.org/10.1021/jacs.4c06068
Abstract in another language
Inorganic ternary metal–C–N compounds with covalently bonded C–N anions encompass important classes of solids such as cyanides and carbodiimides, well known at ambient conditions and composed of [CN]− and [CN2]2– anions, as well as the high-pressure formed guanidinates featuring [CN3]5– anion. At still higher pressures, carbon is expected to be 4-fold coordinated by nitrogen atoms, but hitherto, such CN4-built anions are missing. In this study, four polycarbonitride compounds (LaCN3, TbCN3, CeCN5, and TbCN5) are synthesized in laser-heated diamond anvil cells at pressures between 90 and 111 GPa. Synchrotron single-crystal X-ray diffraction (SCXRD) reveals that their crystal structures are built of a previously unobserved anionic single-bonded carbon–nitrogen three-dimensional (3D) framework consisting of CN4 tetrahedra connected via di- or oligo-nitrogen linkers. A crystal-chemical analysis demonstrates that these polycarbonitride compounds have similarities to lanthanide silicon phosphides. Decompression experiments reveal the existence of LaCN3 and CeCN5 compounds over a very large pressure range. Density functional theory (DFT) supports these discoveries and provides further insight into the stability and physical properties of the synthesized compounds.