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Singh, Shashank ; Kundu, Arindam ; Empel, Claire ; Koenigs, Rene M. ; Singh, Ravi P.:
A radical approach towards polarity-reversed para-substitution of electron-deficient arenes.
In: Chemical Communications.
Bd. 61
(2025)
.
- S. 3888-3891.
ISSN 1364-548X
DOI: https://doi.org/10.1039/D4CC04914D
Abstract
We have developed a protocol for polarity-reversed para-substitution of electron-deficient arenes. In order to achieve desired reactivity and selectivity for a broad range of substrates, the dual pronged strategy is essential. Furthermore, this approach has also shown promise in perfluoroalkylation of arenes. Control experiments and computational studies provide a mechanistic insight for the observed selectivity. The potential for drug design synthesis has been showcased by this economical and ecofriendly method that provides access to a variety of building blocks.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 28 Mär 2025 07:29 |
| Letzte Änderung: | 28 Mär 2025 07:29 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93015 |