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Kloene, Lennard ; Jana, Sripati ; Empel, Claire ; Koenigs, Rene M.:
Aryl/aryl diazoalkanes in rhodium(II)-catalyzed rearrangements of sulfur ylides.
In: Australian Journal of Chemistry.
Bd. 76
(2023)
.
- S. 25-29.
ISSN 1445-0038
DOI: https://doi.org/10.1071/CH22168
Abstract
Sigmatropic rearrangement reactions are of prime interest in the construction of small complex molecules and find widespread application in drug discovery and natural product synthesis. Herein, we report on the application of aryl/aryl diazoalkanes in rhodium-catalyzed sigmatropic rearrangement reactions of allyl sulfides. Overall, a broad variety of different allyl sulfides and different aryl/aryl diazoalkanes were compatible and the desired products were obtained in high yield.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Keywords: | [2,3]‐sigmatropic; aryl/aryl diazoalkanes; carbene; catalysis; diazoalkane; rearrangement; rhodium; ylides |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 28 Mär 2025 10:35 |
| Letzte Änderung: | 28 Mär 2025 10:35 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93045 |