at Google ScholarTitle data
Kloene, Lennard ; Jana, Sripati ; Empel, Claire ; Koenigs, Rene M.:
Aryl/aryl diazoalkanes in rhodium(II)-catalyzed rearrangements of sulfur ylides.
In: Australian Journal of Chemistry.
Vol. 76
(2023)
.
- pp. 25-29.
ISSN 1445-0038
DOI: https://doi.org/10.1071/CH22168
Abstract in another language
Sigmatropic rearrangement reactions are of prime interest in the construction of small complex molecules and find widespread application in drug discovery and natural product synthesis. Herein, we report on the application of aryl/aryl diazoalkanes in rhodium-catalyzed sigmatropic rearrangement reactions of allyl sulfides. Overall, a broad variety of different allyl sulfides and different aryl/aryl diazoalkanes were compatible and the desired products were obtained in high yield.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | [2,3]‐sigmatropic; aryl/aryl diazoalkanes; carbene; catalysis; diazoalkane; rearrangement; rhodium; ylides |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 28 Mar 2025 10:35 |
| Last Modified: | 10 Mar 2026 08:37 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93045 |