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Empel, Claire ; Pei, Chao ; Koenigs, Rene M.:
Unlocking novel reaction pathways of diazoalkanes with visible light.
In: Chemical Communications.
Bd. 58
(2022)
.
- S. 2788-2798.
ISSN 1364-548X
DOI: https://doi.org/10.1039/D1CC06521A
Abstract
Photochemistry has recently attracted the interest of synthetic chemists to conduct photolysis reactions of diazoalkanes. In this feature article, we provide a concise overview on this field, starting with discoveries in physical organic chemistry and then discuss examples in organic synthesis of singlet carbene intermediates, ranging from classic reactivity towards advances in cascade reactions and unusual protonation reactions under photochemical conditions. We then commence with a discussion on the electronic control of singlet and triplet carbene intermediates and last discuss the advances that have been made with regards to the reaction of weakly colored diazoalkanes in dye-sensitized reactions to access radical or triplet carbene intermediates.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 01 Apr 2025 08:45 |
| Letzte Änderung: | 01 Apr 2025 08:45 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93099 |