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Empel, Claire ; Jana, Sripati ; Koenigs, Rene M.:
Advances in [1,2]-Sigmatropic Rearrangements of Onium Ylides via Carbene Transfer Reactions.
In: Synthesis.
Bd. 53
(2021)
.
- S. 4567-4587.
ISSN 0039-7881
DOI: https://doi.org/10.1055/a-1577-5864
Abstract
This review article summarizes progress made on [1,2]-sigmatropic rearrangements using carbenes in the ylide formation step. While other rearrangements, such as the [2,3]-sigmatropic, Doyle–Kirmse, or Sommelet–Hauser rearrangements, have been studied in detail over the past decades, investigations on [1,2]-sigmatropic rearrangements are still limited. Based on the application of diazoalkanes as carbene precursors, research on diazoalkanes in ylide formation reactions started flourishing in the 1990s. This Short Review covers milestones from the advent of [1,2]-sigmatropic rearrangements using carbenes to generate ammonium, oxonium and other ylide species, and should serve as an overview to further promote research in this area.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Keywords: | Stevens rearrangement; diazoalkanes; carbenes; carbene transfer reaction; ylides; [1,2]-sigmatropic rearrangement |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 01 Apr 2025 11:29 |
| Letzte Änderung: | 01 Apr 2025 11:29 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93113 |