bei Google ScholarTitelangaben
Li, Fang ; Pei, Chao ; Quaranta, Calogero ; Koenigs, Rene M.:
1,3‐Difunctionalization of Imino‐Carbenes via Rhodium‐Catalyzed Reactions of Triazoles with Acyl Selenides.
In: Advanced Synthesis & Catalysis.
Bd. 363
(2021)
.
- S. 4365-4370.
ISSN 1615-4169
DOI: https://doi.org/10.1002/adsc.202100629
Abstract
Herein, we report on the rhodium-catalyzed reaction of triazoles with acyl selenides. Under thermal reaction conditions and in the presence of a rhodium catalyst, a rapid 1,3-difunctionalization reaction occurs to provide valuable α-seleno enamides with high stereoselectivity and broad functional group tolerance, which was demonstrated in 35 examples with up to 95% yield. Computational calculations suggest a reaction pathway that gives a direct access to the 1,3-difunctionalization without intermittent formation of ylide intermediates.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 01 Apr 2025 11:32 |
| Letzte Änderung: | 01 Apr 2025 11:32 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93114 |