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Bera, Sourav Sekhar ; Bahukhandi, Srishti Ballabh ; Empel, Claire ; Koenigs, Rene M.:
Catalyst-controlled site-selective N–H and C3-arylation of carbazole via carbene transfer reactions.
In: Chemical Communications.
Bd. 57
(2021)
.
- S. 6193-6196.
ISSN 1364-548X
DOI: https://doi.org/10.1039/D1CC01863A
Abstract
A site-selective direct arylation reaction of carbazole and other N-heterocycles with diazo-naphthalen-2(1H)-ones has been developed. While Au(I)-NHC catalysts lead to selective C3-arylation, palladium acetate allows for selective N–H arylation, displaying complete site-selectivity each. To show the applicability of these arylation reactions, one-pot, two-fold diarylation reactions of carbazole were demonstrated.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 01 Apr 2025 11:41 |
| Letzte Änderung: | 01 Apr 2025 11:41 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93115 |