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Catalyst-controlled site-selective N–H and C3-arylation of carbazole via carbene transfer reactions

Title data

Bera, Sourav Sekhar ; Bahukhandi, Srishti Ballabh ; Empel, Claire ; Koenigs, Rene M.:
Catalyst-controlled site-selective N–H and C3-arylation of carbazole via carbene transfer reactions.
In: Chemical Communications. Vol. 57 (2021) . - pp. 6193-6196.
ISSN 1364-548X
DOI: https://doi.org/10.1039/D1CC01863A

Abstract in another language

A site-selective direct arylation reaction of carbazole and other N-heterocycles with diazo-naphthalen-2(1H)-ones has been developed. While Au(I)-NHC catalysts lead to selective C3-arylation, palladium acetate allows for selective N–H arylation, displaying complete site-selectivity each. To show the applicability of these arylation reactions, one-pot, two-fold diarylation reactions of carbazole were demonstrated.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 01 Apr 2025 11:41
Last Modified: 07 Oct 2025 10:57
URI: https://eref.uni-bayreuth.de/id/eprint/93115