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Brønsted acid‐catalyzed Reactions of Unprotected N‐heterocycles with Aryl/Aryl Diazoalkanes

Titelangaben

Bahukhandi, Srishti Ballabh ; Jana, Sripati ; Koenigs, Rene M.:
Brønsted acid‐catalyzed Reactions of Unprotected N‐heterocycles with Aryl/Aryl Diazoalkanes.
In: Asian Journal of Organic Chemistry. Bd. 10 (2021) . - S. 571-575.
ISSN 2193-5815
DOI: https://doi.org/10.1002/ajoc.202000709

Abstract

The chemoselective C−H functionalization of unprotected N-heterocycles is a challenging task in organic synthesis. Herein, we report on a Brønsted-acid catalyzed reaction of aryl/aryl diazoalkanes with unprotected N-heterocycles to selectively allow for C−H functionalization at the C3-position under mild reaction conditions and short reaction time without the need of protecting groups. The general applicability of this method was further expanded towards protected indole and unprotected pyrrole heterocycles.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 01 Apr 2025 11:47
Letzte Änderung: 01 Apr 2025 11:47
URI: https://eref.uni-bayreuth.de/id/eprint/93117