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Jana, Sripati ; Guo, Yujing ; Koenigs, Rene M.:
Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions.
In: Chemistry : a European Journal.
Bd. 27
(2021)
.
- S. 1270-1281.
ISSN 1521-3765
DOI: https://doi.org/10.1002/chem.202002556
Abstract
Among the available methods to increase the molecular complexity, sigmatropic rearrangements occupy a distinct position in organic synthesis. Despite being known for over a century sigmatropic rearrangement reactions of ylides via carbene transfer reaction have only recently come of age. Most of the ylide mediated rearrangement processes involve rupture of a σ-bond and formation of a new bond between π-bond and negatively charged atom followed by simultaneous redistribution of π-electrons. This minireview describes the advances in this research area made in recent years, which now opens up metal-catalyzed enantioselective sigmatropic rearrangement reactions, metal-free photochemical rearrangement reactions and novel reaction pathways that can be accessed via ylide intermediates.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 01 Apr 2025 11:54 |
| Letzte Änderung: | 01 Apr 2025 11:54 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93119 |