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Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions

Titelangaben

Jana, Sripati ; Guo, Yujing ; Koenigs, Rene M.:
Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions.
In: Chemistry : a European Journal. Bd. 27 (2021) . - S. 1270-1281.
ISSN 1521-3765
DOI: https://doi.org/10.1002/chem.202002556

Abstract

Among the available methods to increase the molecular complexity, sigmatropic rearrangements occupy a distinct position in organic synthesis. Despite being known for over a century sigmatropic rearrangement reactions of ylides via carbene transfer reaction have only recently come of age. Most of the ylide mediated rearrangement processes involve rupture of a σ-bond and formation of a new bond between π-bond and negatively charged atom followed by simultaneous redistribution of π-electrons. This minireview describes the advances in this research area made in recent years, which now opens up metal-catalyzed enantioselective sigmatropic rearrangement reactions, metal-free photochemical rearrangement reactions and novel reaction pathways that can be accessed via ylide intermediates.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 01 Apr 2025 11:54
Letzte Änderung: 01 Apr 2025 11:54
URI: https://eref.uni-bayreuth.de/id/eprint/93119