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Empel, Claire ; Jana, Sripati ; Koenigs, Rene M.:
C-H Functionalization via Iron-Catalyzed Carbene-Transfer Reactions.
In: Molecules.
Bd. 25
(2020)
.
- 880.
ISSN 1420-3049
DOI: https://doi.org/10.3390/molecules25040880
Abstract
The direct C-H functionalization reaction is one of the most efficient strategies by which to introduce new functional groups into small organic molecules. Over time, iron complexes have emerged as versatile catalysts for carbine-transfer reactions with diazoalkanes under mild and sustainable reaction conditions. In this review, we discuss the advances that have been made using iron catalysts to perform C-H functionalization reactions with diazoalkanes. We give an overview of early examples employing stoichiometric iron carbene complexes and continue with recent advances in the C-H functionalization of C(sp2)-H and C(sp3)-H bonds, concluding with the latest developments in enzymatic C-H functionalization reactions using iron-heme-containing enzymes.
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| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Keywords: | iron; carbene; diazoalkane; C-H functionalization |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 02 Apr 2025 09:16 |
| Letzte Änderung: | 02 Apr 2025 09:16 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93147 |