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Empel, Claire ; Koenigs, Rene M.:
Continuous-flow photochemical carbene transfer reactions.
In: Journal of Flow Chemistry.
Bd. 10
(2020)
.
- S. 157-160.
ISSN 2063-0212
DOI: https://doi.org/10.1007/s41981-019-00054-9
Abstract
Photochemistry constitutes an important tool to conduct environmentally benign and efficient transformations in organic synthesis. Conventional batch transformations are limited in productivity and scale due to Beer’s law, which can be easily overcome using flow chemistry approaches. Herein, we report on the continuous-flow photolysis of aryl diazoacetates using a glass microreactor and blue LEDs. Following this methodology, we were able to demonstrate the application of continuous-flow chemistry in photochemical cyclopropanation and rearrangement reactions and demonstrate the scalability of photochemical carbene transfer reactions.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 02 Apr 2025 09:22 |
| Letzte Änderung: | 02 Apr 2025 09:22 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93149 |