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Empel, Claire ; Koenigs, Rene M.:
Sustainable Carbene Transfer Reactions with Iron and Light.
In: Synlett.
Bd. 30
(2019)
.
- S. 1929-1934.
ISSN 1437-2096
DOI: https://doi.org/10.1055/s-0037-1611874
Abstract
Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We recently reported on our findings on safe and scalable applications of hazardous diazoacetonitrile using cheap and commercially available iron catalysts in efficient carbene transfer reactions, ranging from cyclopropanation towards C–H functionalization reactions for the synthesis of biologically important building blocks. More lately, we uncovered the reactivity of diazoalkanes under photochemical conditions using visible light and were able to demonstrate a variety of different, metal-free carbene transfer reactions, which now open up new sustainable ways for the construction of small functional molecules.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Keywords: | carbene transfer reactions; cycloaddition; rearrangement; C–H functionalization; diazoalkanes; iron; photochemistry |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 02 Apr 2025 12:35 |
| Letzte Änderung: | 02 Apr 2025 12:35 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93173 |