at Google ScholarTitle data
Empel, Claire ; Koenigs, Rene M.:
Sustainable Carbene Transfer Reactions with Iron and Light.
In: Synlett.
Vol. 30
(2019)
.
- pp. 1929-1934.
ISSN 1437-2096
DOI: https://doi.org/10.1055/s-0037-1611874
Abstract in another language
Carbenes are versatile, highly reactive intermediates with great importance in chemistry. We recently reported on our findings on safe and scalable applications of hazardous diazoacetonitrile using cheap and commercially available iron catalysts in efficient carbene transfer reactions, ranging from cyclopropanation towards C–H functionalization reactions for the synthesis of biologically important building blocks. More lately, we uncovered the reactivity of diazoalkanes under photochemical conditions using visible light and were able to demonstrate a variety of different, metal-free carbene transfer reactions, which now open up new sustainable ways for the construction of small functional molecules.
Further data
| Item Type: | Article in a journal |
|---|---|
| Refereed: | Yes |
| Keywords: | carbene transfer reactions; cycloaddition; rearrangement; C–H functionalization; diazoalkanes; iron; photochemistry |
| Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry - Univ.-Prof. Dr. René M. Koenigs Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry II - Bioorganic Chemistry |
| Result of work at the UBT: | No |
| DDC Subjects: | 500 Science > 540 Chemistry |
| Date Deposited: | 02 Apr 2025 12:35 |
| Last Modified: | 07 Oct 2025 11:40 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93173 |