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Photoredox Catalysis as an Efficient Tool for the Aerobic Oxidation of Amines and Alcohols: Bioinspired Demethylations and Condensations

Titelangaben

Rueping, Magnus ; Vila, Carlos ; Szadkowska, Anna ; Koenigs, Rene M. ; Fronert, Jeanne:
Photoredox Catalysis as an Efficient Tool for the Aerobic Oxidation of Amines and Alcohols: Bioinspired Demethylations and Condensations.
In: ACS Catalysis. Bd. 2 (2012) . - S. 2810-2815.
ISSN 2155-5435
DOI: https://doi.org/10.1021/cs300604k

Abstract

Tertiary amines were readily converted into secondary amines through a photoredox-catalyzed N-demethylation, a bioinspired procedure that resembles nature’s enzymatic pathways. Furthermore, the selective oxidation of primary amines as well as primary and secondary alcohols was achieved using photoredox catalysis. The protocols feature low catalyst loadings (1–2 mol %) and offer access to diverse imines and carbonyl compounds.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: visible light; N-demethylation; oxidation; oxygen; organic dye; cross dehydrogenative coupling
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 03 Apr 2025 11:33
Letzte Änderung: 03 Apr 2025 11:33
URI: https://eref.uni-bayreuth.de/id/eprint/93205