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Unifying Metal and Brønsted Acid Catalysis : Concepts, Mechanisms, and Classifications

Titelangaben

Rueping, Magnus ; Koenigs, Rene M. ; Atodiresei, Iuliana:
Unifying Metal and Brønsted Acid Catalysis : Concepts, Mechanisms, and Classifications.
In: Chemistry : a European Journal. Bd. 16 (2010) . - S. 9350-9365.
ISSN 1521-3765
DOI: https://doi.org/10.1002/chem.201001140

Abstract

Asymmetric catalysis is a key feature of modern synthetic organic chemistry. Traditionally, different combinations of ligands and metals are used to perform highly enantioselective reactions. Since the renaissance of organocatalysis in the early 2000s, tremendous improvement in the field of metal-free catalysis has been achieved. Recently, the combination of transition metals and organocatalysts has allowed the development of new protocols enabling transformations that could not previously be realized. This article aims to present the latest contributions in the field of combined chiral Brønsted acid and metal catalyzed reactions, highlighting the advantages of these catalytic systems as well as describing the uncertainties regarding the molecular structure of the catalytically active species and the reaction mechanisms.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 03 Apr 2025 12:31
Letzte Änderung: 03 Apr 2025 12:31
URI: https://eref.uni-bayreuth.de/id/eprint/93215