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Reiter, Felix ; Pielmeier, Markus ; Vogel, Anna ; Jandl, Christian ; Plodinec, Milivoj ; Rohner, Christian ; Lunkenbein, Thomas ; Nisi, Katharina ; Holleitner, Alexander ; Nilges, Tom:
SnBrP-A SnIP-type representative in the Sn-Br-P system.
In: Zeitschrift für anorganische und allgemeine Chemie.
Bd. 648
(2022)
Heft 10, SI
.
- e202100347.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.202100347
Abstract
One-dimensional semiconductors are interesting materials due to their unique structural features and anisotropy, which grant them intriguing optical, dielectric and mechanical properties. In this work, we report on SnBrP, a lighter homologue of the first inorganic double helix compound SnIP. This class of compounds is characterized by intriguing mechanical and electronic properties, featuring a high flexibility without modulation of physical properties. Semiconducting SnBrP can be synthesized from red phosphorus, tin and tin(II)bromide at elevated temperatures and crystallizes as red-orange, cleavable needles. Raman measurements pointed towards a double helical building unit in SnBrP, showing similarities to the SnIP structure. After taking PL measurements, HR-TEM, and quantum chemical calculations into account, we were able to propose a sense full structure model for SnBrP.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Zusätzliche Informationen: | WOS:000740082900001 |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 12 Jun 2025 13:00 |
| Letzte Änderung: | 12 Jun 2025 13:00 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93683 |
