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Li, Xuan ; Lunkenbein, Thomas ; Kröhnert, Jutta ; Pfeifer, Verena ; Girgsdies, Frank ; Rosowski, Frank ; Schlögl, Robert ; Trunschke, Annette:
Hydrothermal synthesis of bi-functional nanostructured manganese tungstate catalysts for selective oxidation.
In: Faraday Discussions.
Bd. 188
(2016)
.
- S. 99-113.
ISSN 1364-5498
DOI: https://doi.org/10.1039/c5fd00191a
Abstract
The mechanism of C-H activation in selective oxidation reactions of short-chain alkane molecules over transition metal oxides is critically affected by the balance of acid-base and redox sites at the surface of the catalyst. Using the example of manganese tungstate we discuss how the relative abundance of these sites can be controlled via synthetic techniques. Phase-pure catalysts composed of the thermodynamic stable monoclinic MnWO4 phase have been prepared using hydrothermal synthesis. Variation of the initial pH value resulted in rod-shaped nano-crystalline MnWO4 catalysts composed of particles with varying aspect ratio. The synthesis products have been analysed using transmission electron microscopy, X-ray diffraction, infrared, and photoelectron spectroscopy. In situ Raman spectroscopy was used to investigate the dissolution-re-crystallization processes occurring under hydrothermal conditions. Ethanol oxidation was applied to probe the surface functionalities in terms of acid-base and redox properties. Changes in the aspect ratio of the primary catalyst particles are reflected in the product distribution induced by altering the fraction of acid-base and redox sites exposed at the surface of the catalysts in agreement with the proposed mechanism of particle growth by re-crystallization during ageing under hydrothermal conditions.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Zusätzliche Informationen: | WOS:000380099200007 |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 12 Jun 2025 11:21 |
| Letzte Änderung: | 12 Jun 2025 11:21 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/93732 |