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Decomposition synthesis of tuneable, macroporous carbon foams from crystalline precursors via in situ templating

Titelangaben

Ressnig, D. ; Corbiere, T. ; Lunkenbein, Thomas ; Braun, U. ; Willinger, M. G. ; Antonietti, M.:
Decomposition synthesis of tuneable, macroporous carbon foams from crystalline precursors via in situ templating.
In: Journal of Materials Chemistry A. Bd. 2 (2014) Heft 42 . - S. 18076-18081.
ISSN 2050-7496
DOI: https://doi.org/10.1039/c4ta03646h

Abstract

A flexible, sustainable, one-step thermal decomposition route for the synthesis of hierarchical, heteroatom doped carbon foams is presented. Task-specific semi-organic crystals combine functions for three different purposes: the carbon and heteroatom source, a foaming agent (CO2) and an in situ generable template (NaCl). Insights to the decomposition pathway were gained through FTIR/MS coupled TGA and an ultrafast out-of-furnace heating procedure and the products were analysed with (HR)SEM/TEM, EELS, FTIR, and N-2 sorption. The resulting macroporous carbon foams are excellent supports for metallic nanoparticles due to their hierarchical structure, high surface area and tuneable heteroatom contents. This was demonstrated for catalytically active copper or the magnetic CoNi alloy for water purification.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Zusätzliche Informationen: WOS:000343961300047
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 12 Jun 2025 11:10
Letzte Änderung: 12 Jun 2025 11:10
URI: https://eref.uni-bayreuth.de/id/eprint/93740