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Decomposition synthesis of tuneable, macroporous carbon foams from crystalline precursors via in situ templating

Title data

Ressnig, D. ; Corbiere, T. ; Lunkenbein, Thomas ; Braun, U. ; Willinger, M. G. ; Antonietti, M.:
Decomposition synthesis of tuneable, macroporous carbon foams from crystalline precursors via in situ templating.
In: Journal of Materials Chemistry A. Vol. 2 (2014) Issue 42 . - pp. 18076-18081.
ISSN 2050-7496
DOI: https://doi.org/10.1039/c4ta03646h

Abstract in another language

A flexible, sustainable, one-step thermal decomposition route for the synthesis of hierarchical, heteroatom doped carbon foams is presented. Task-specific semi-organic crystals combine functions for three different purposes: the carbon and heteroatom source, a foaming agent (CO2) and an in situ generable template (NaCl). Insights to the decomposition pathway were gained through FTIR/MS coupled TGA and an ultrafast out-of-furnace heating procedure and the products were analysed with (HR)SEM/TEM, EELS, FTIR, and N-2 sorption. The resulting macroporous carbon foams are excellent supports for metallic nanoparticles due to their hierarchical structure, high surface area and tuneable heteroatom contents. This was demonstrated for catalytically active copper or the magnetic CoNi alloy for water purification.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: WOS:000343961300047
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Operando-Analytics of Electrochemical Energy Storage > Chair Operando-Analytics of Electrochemical Energy Storage - Univ.-Prof. Dr. Thomas Lunkenbein
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 12 Jun 2025 11:10
Last Modified: 04 Jul 2025 11:32
URI: https://eref.uni-bayreuth.de/id/eprint/93740