Thermophysical Properties of Silicon Oxide Nanoparticles in Water and Ethylene Glycol–Water Dispersions

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Wittmann, Franz ; Arnautovic, Zlatan ; Heberle, Florian ; Brüggemann, Dieter:
Thermophysical Properties of Silicon Oxide Nanoparticles in Water and Ethylene Glycol–Water Dispersions.
In: Fluids. Bd. 9 (2024) Heft 11 . - 261.
ISSN 2311-5521
DOI: https://doi.org/10.3390/fluids9110261

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Abstract

Measurements of transmission as well as thermophysical properties have been carried out for different concentrations of SiO2 nanoparticles (0, 1, 2, 5, 10, and 20 wt.) in pure water (W) and ethylene glycol–water mixture (EG/W) in a weight ratio of 25/75, from 298 to 323 K at 100 kPa. In particular, the density, specific heat capacity, and thermal diffusivity are measured by a density meter, differential scanning calorimetry, and the laser flash method. In the case of 20 wt. SiO2, transmission in the visible range is reduced by 9.3. Simultaneously, the density rises linearly to 12.3 (in W) and 11.3 (in EG/W). The specific heat capacity decreases to 15.9 (in W) and 17.3 (in EG/W), while the thermal diffusivity rises to 16.4 (in W) and 20.4 (in EG/W). While the density measurements are in very good agreement with the literature, the measured values of the specific heat capacity deviate more than 5, especially for concentrations below 5 wt. SiO2. Moreover, it is shown that the thermal conductivity increases less for fluids in small gaps compared to other authors, which could be due to the suppression of the Brownian motion. Based on the measurement results, temperature- and concentration-dependent correlations for the investigated thermophysical properties are developed using two adjustable parameters. In general, these correlations show deviations of less than 4 from the experimental results, which will help to fill the gaps in the variation of experimental results due to size, SiO2 nanofluid production, and different measurement devices, and thus optimize solar thermal applications with SiO2 nanofluid.