Synthesis and characterisation of graft co-polymers of derivatives of poly(p-xylylene)

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Madan, R. ; Greiner, Andreas:
Synthesis and characterisation of graft co-polymers of derivatives of poly(p-xylylene).
In: Designed Monomers and Polymers. Bd. 9 (2006) Heft 1 . - S. 81-87.
ISSN 1568-5551
DOI: https://doi.org/10.1163/156855506775526214

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Abstract

Soluble derivatives of poly(p-xylylene) (PPX) were obtained by chemical vapour deposition polymerization and by Gilch-type polymerization. These PPX derivatives were chloromethylated by treatment with paraform aldehyde in the presence of trichloromethyl silane and stannic chloride. The chloromethylated PPX derivatives were reacted with anionic living poly(E-caprolactone) to form corresponding graft co-polymers.