Title data
Agarwal, Seema ; Xie, Xiulan:
SmI₂/Sm-Based γ-Buyrolactone−ε-Caprolactone Copolymers: Microstructural Characterization Using One- and Two-Dimensional NMR Spectroscopy.
In: Macromolecules.
Vol. 36
(2003)
Issue 10
.
- pp. 3545-3549.
ISSN 1520-5835
DOI: https://doi.org/10.1021/ma0258713
Abstract in another language
Copolymers containing nonhomopolymerizable γ-butyrolactone (BL) and ε-caprolactone (CL) units of different compositions were synthesized by the ring-opening polymerization method using the SmI2/Sm initiator system. A maximum of 33 mol % of BL was incorporated into polycaprolactone (PCL) backbone. The microstructure of these copolymers was analyzed by one- and two-dimensional NMR spectroscopies. The overlapped methylene proton signals of CL and BL were resolved using 2D 1H−13C heteronuclear multibond correlation (HMBC) and homonuclear 1H−1H total correlation spectroscopy (TOCSY) techniques. The triad sequence distribution centered at the carbonyl carbon and methylene carbon of CL and BL has been obtained from 13C NMR spectroscopy. Further, 1D and 2D NMR spectroscopic techniques were used to confirm the change of microstructure from PCL blocks separated by discrete BL units to random copolymer structure having BL−BL units with increase in the mole percent of BL units in the copolymer.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Keywords: | RING-OPENING POLYMERIZATION; ETHYLENE CARBONATE; DELTA-VALEROLACTONE; SAMARIUM COMPLEXES; LACTONES; BUTYROLACTONE; BIODEGRADABILITY; GLYCOLIDE |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Profile Fields > Advanced Fields > Polymer and Colloid Science Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Profile Fields Profile Fields > Advanced Fields |
Result of work at the UBT: | No |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 07 Apr 2015 11:36 |
Last Modified: | 28 Jul 2023 09:12 |
URI: | https://eref.uni-bayreuth.de/id/eprint/9906 |