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Synthesis and X-Ray Structure of Bis-Trifluormethyl-N,N- Diethyldithiocarbamato Copper; A Remarkably Stable Copper (III) Perfluoroalkylcopper Complex

Title data

Willert-Porada, Monika ; Burton, Donald J. ; Baenziger, Norman C.:
Synthesis and X-Ray Structure of Bis-Trifluormethyl-N,N- Diethyldithiocarbamato Copper; A Remarkably Stable Copper (III) Perfluoroalkylcopper Complex.
In: Chemical Communications. (January 1989) Issue 21 . - pp. 1633-1634.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C39890001633

Official URL: Volltext

Abstract in another language

The reaction between trifluoromethylcadmium reagent and Br₂Cu(edtc)(edtc =N,N-diethyldithiocarbamato) or CdI+[(CF₃)₂Cu]– with [Et₂NC(S)S]₂ in DMF (dimethylformamide) at –30°C yields the stable CuIII perfluoroalkylcopper complex, (CF₃)₂CuSC(S)NEt₂.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Ehemalige Professoren > Chair Materials Processing - Univ.-Prof. Dr. Monika Willert-Porada
Faculties
Faculties > Faculty of Engineering Science > Ehemalige Professoren
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 500 Natural sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 22 Aug 2017 06:48
Last Modified: 22 Aug 2017 06:48
URI: https://eref.uni-bayreuth.de/id/eprint/11801