Synthesis and X-Ray Structure of Bis-Trifluormethyl-N,N- Diethyldithiocarbamato Copper; A Remarkably Stable Copper (III) Perfluoroalkylcopper Complex

Titelangaben

Willert-Porada, Monika ; Burton, Donald J. ; Baenziger, Norman C.:
Synthesis and X-Ray Structure of Bis-Trifluormethyl-N,N- Diethyldithiocarbamato Copper; A Remarkably Stable Copper (III) Perfluoroalkylcopper Complex.
In: Chemical Communications. (1989) Heft 21 . - S. 1633-1634.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C39890001633

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Abstract

The reaction between trifluoromethylcadmium reagent and Br₂Cu(edtc)(edtc =N,N-diethyldithiocarbamato) or CdI+[(CF₃)₂Cu]– with [Et₂NC(S)S]₂ in DMF (dimethylformamide) at –30°C yields the stable CuIII perfluoroalkylcopper complex, (CF₃)₂CuSC(S)NEt₂.