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Design and Implementation of a Reactor Setup for Combinatorial Anionic Synthesis of Block Copolymer Series with well-defined Compositions

Title data

Pettau, Robin ; Erdelen, Christian H. ; Schmidt, Hans-Werner:
Design and Implementation of a Reactor Setup for Combinatorial Anionic Synthesis of Block Copolymer Series with well-defined Compositions.
In: Macromolecular Reaction Engineering. Vol. 4 (January 2010) Issue 1 . - pp. 65-72.
ISSN 1862-8338
DOI: https://doi.org/10.1002/mren.200900037

Official URL: Volltext

Project information

Project financing: Deutsche Forschungsgemeinschaft

Abstract in another language

We present a combinatorial approach to the synthesis of block copolymer series by anionic polymerization, utilizing a specially designed reactor setup. The setup features one main reactor and three secondary reactors to carry out anionic polymerizations on laboratory-scale quantities at low temperatures. The implementation was demonstrated with three series of AB- and ABC-block copolymers with identical A- and AB-blocks, respectively. The B-block in AB-diblock copolymers and the C-block in ABC-triblock copolymers can be varied with respect to block length or chemical constitution. Well-defined series of block copolymers are useful for advanced optimization of functional block copolymers in nanotechnology applications.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I > Chair Macromolecular Chemistry I - Univ.-Prof. Dr. Hans-Werner Schmidt
Profile Fields
Profile Fields > Advanced Fields
Profile Fields > Advanced Fields > Polymer and Colloid Science
Research Institutions
Research Institutions > Research Centres
Research Institutions > Research Centres > Bayreuth Institute of Macromolecular Research - BIMF
Research Institutions > Research Centres > Bayreuth Center for Colloids and Interfaces - BZKG
Research Institutions > Collaborative Research Centers, Research Unit
Research Institutions > Collaborative Research Centers, Research Unit > SFB 481 Komplexe Makromolekül- und Hybridsysteme in inneren und äußeren Feldern
Graduate Schools
Graduate Schools > Elite Network Bavaria
Graduate Schools > Elite Network Bavaria > Macromolecular Science
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jun 2015 09:23
Last Modified: 25 Jun 2015 09:23
URI: https://eref.uni-bayreuth.de/id/eprint/1259