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Hierarchically Structured Spherulitic Cobalt Hydroxide Carbonate as a Precursor to Ordered Nanostructures of Electrocatalytically Active Co₃O₄

Title data

Schenk, Anna ; Goll, Miriam ; Reith, Lukas ; Roussel, Manuel ; Blaschkowski, Björn ; Rosenfeldt, Sabine ; Yin, Xiaofei ; Schmahl, Wolfgang W. ; Ludwigs, Sabine:
Hierarchically Structured Spherulitic Cobalt Hydroxide Carbonate as a Precursor to Ordered Nanostructures of Electrocatalytically Active Co₃O₄.
In: Crystal Growth & Design. (8 September 2020) .
ISSN 1528-7505
DOI: https://doi.org/10.1021/acs.cgd.0c00576

Project information

Project financing: Deutsche Forschungsgemeinschaft
SFB 840 - TPB9

Abstract in another language

With their tendency to form low-dimensional materials with high surface area, cobalt hydroxide carbonates represent an important class of precursors to Co3O4—a heterogeneous catalyst with various applications including sustainable energy conversion. We here present a facile methodology for the room temperature precipitation of cobalt hydroxide carbonate under additive-free conditions. Upon aging in aqueous solution, the initially deposited amorphous bulk solid slowly transforms into macroscopic crystals with an unusual spherulitic morphology interfacially templated by glass surfaces. Most intriguingly, the individual branches of these hemispherical particles represent highly anisometric, elongated platelets reaching millimeter dimensions along the growth direction, while their lamellar architecture indicates the formation of a layered double hydroxide structure. Gradual substitution of Co(II) with Mn(II) results in the deposition of spheroidal stoichiometric carbonates with a calcite structure, in which the crystal lattice progressively expands with increasing Mn content. Replacement of Co(II) by Ni(II), in contrast, preserves the spherulite morphology at low Ni(II) content (Co/Ni > 1), but prevents precipitate maturation at higher proportions of Ni(II). Calcination converts the hydroxide carbonate precursor into hierarchical Co3O4 spherulites with superstructures composed of interconnected nanoparticles, where this nanoscale arrangement is shown to positively affect the electrocatalytic activity toward the oxygen evolution reaction.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Junior Professor Colloidal Systems > Junior Professor Colloidal Systems - Juniorprof. Dr. Anna Schenk
Profile Fields > Advanced Fields > Polymer and Colloid Science
Research Institutions > Affiliated Institutes > Bavarian Polymer Institute (BPI)
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 11 Sep 2020 06:50
Last Modified: 11 Sep 2020 06:50
URI: https://eref.uni-bayreuth.de/id/eprint/56863